Synthesis and Crystal Structure of 5,15-Bis(3,5-di-tert-butylphenyl)-10-(phenylethynyl)-20-(trimethylsilylethynyl)porphyrin

摘要

The crystal structure of the title compound, C₆₁H₆₆N₄Si(I) displays a highly unsymmetric molecular entity involving three different substituents on the meso-positions. The molecular units in the crystal are intermolecularly bonded to each other via π-π, and CH-π interactions, resulting in the genesis of a 2D structural motif. This compound crystallizes in the triclinic system of the P1 space group with the following cell parameters: a = 8.9729(10), b = 19.167(2), c = 20.763(2)Å; α = 65.932(2)°, β = 81.356(2)°, γ = 86.051(2)°, Z = 2.