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Semiflexible Chains at Surfaces: Worm-Like Chains and beyond

机译:表面的半柔性链:蠕虫状链及其他

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We give an extended review of recent numerical and analytical studies on semiflexible chains near surfaces undertaken at Institut Charles Sadron (sometimes in collaboration) with a focus on static properties. The statistical physics of thin confined layers, strict two-dimensional (2D) layers and adsorption layers (both at equilibrium with the dilute bath and from irreversible chemisorption) are discussed for the well-known worm-like-chain (WLC) model. There is mounting evidence that biofilaments (except stable d-DNA) are not fully described by the WLC model. A number of augmented models, like the (super) helical WLC model, the polymorphic model of microtubules (MT) and a model with (strongly) nonlinear flexural elasticity are presented, and some aspects of their surface behavior are analyzed. In many cases, we use approaches different from those in our previous work, give additional results and try to adopt a more general point of view with the hope to shed some light on this complex field.
机译:我们对查尔斯·萨德隆研究所(有时是合作研究)在表面附近的半柔性链条进行的近期数值和分析研究进行了广泛的回顾,其重点是静态特性。针对众所周知的蠕虫状链(WLC)模型,讨论了薄的受限层,严格的二维(2D)层和吸附层(均与稀浴处于平衡状态且来自不可逆化学吸附)的统计物理学。越来越多的证据表明,WLC模型并未完全描述生物丝(稳定的d-DNA除外)。提出了许多增强模型,例如(超级)螺旋WLC模型,微管多态性模型(MT)和具有(强烈)非线性挠曲弹性的模型,并分析了其表面行为的某些方面。在许多情况下,我们使用与以前工作不同的方法,给出额外的结果,并尝试采用更笼统的观点,以期希望对这一复杂领域有所了解。

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