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Talc filled polylactic‑acid biobased polymer composites: tensile, thermal and morphological properties

机译:滑石粉填充的聚乳酸生物基聚合物复合材料:拉伸,热和形态性能

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摘要

Global warming due to human activities (i.e., burning fossil fuels) has led to many issues, such as extreme weather (storm or drought) and rise in sea level making low land uninhabitable. One of the solutions to mitigate the global warming is to promote the use of biobased material. In this work, various dosage of talc powder ranged from 5, 10, 30 and 40 wt% were added into polylactic acid (PLA) to form biobased polymer composites. The biobased polymer composite has the potential to replace fossil-based polymer for sustainable packaging application. The PLA/talc composites were prepared by using melt blending method and compressed into thin sheet for characterisation test. The effect of talc content on the thermal properties and tensile performance of the PLA composites were investigated. Scanning electron microscope was used to study the fracture surface of the composites and the dispersion of talc powder in the matrix. Results showed that the addition of talc ranged from 5 to 30 wt% can enhance the Young’s modulus and thermal stability of the composites but there is no improvement in tensile strength and elongation at break due to poor interfacial adhesion. The addition of talc beyond 30 wt% (i.e., 40 wt%) did not show improvement in thermal stability because at high talc content, the formation of agglomerate and voids allows the oxygen to diffuse into the matrix which lead to decomposition process.
机译:人类活动(即燃烧化石燃料)引起的全球变暖导致许多问题,例如极端天气(暴风雨或干旱)和海平面上升使得低地无法居住。缓解全球变暖的解决方案之一是促进生物基材料的使用。在这项工作中,将滑石粉的5、10、30和40 wt%范围内的各种剂量添加到聚乳酸(PLA)中,以形成生物基聚合物复合材料。这种生物基聚合物复合材料具有替代矿物基聚合物用于可持续包装应用的潜力。采用熔融共混法制备了PLA /滑石粉复合材料,并将其压缩成薄片进行表征测试。研究了滑石粉含量对PLA复合材料的热性能和拉伸性能的影响。用扫描电子显微镜研究了复合材料的断裂表面以及滑石粉在基体中的分散情况。结果表明,添加5至30 wt%的滑石粉可以提高复合材料的杨氏模量和热稳定性,但由于界面粘合性差,因此拉伸强度和断裂伸长率没有改善。超过30重量%(即40重量%)的滑石的添加没有显示出热稳定性的改善,因为在高滑石含量下,附聚物和空隙的形成允许氧扩散到基质中,从而导致分解过程。

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