Mechanochemically synthesized CsH2PO4–H3PW12O40 composites as proton-conducting electrolytes for fuel cell systems in a dry atmosphere

摘要

Cesium dihydrogen phosphate ( CsH₂PO₄ , CDP) and dodecaphosphotungstic acid ( H₃PW₁₂O₄₀ nH₂O , WPA nH₂O ) were mechanochemically milled to synthesize CDP–WPA composites. The ionic conductivities of these composites were measured by an ac impedance method under anhydrous conditions. Despite the synthesis temperatures being much lower than the dehydration and phase-transition temperatures of CDP under anhydrous conditions, the ionic conductivities of the studied composites increased significantly. The highest ionic conductivity of 6.58×10^?4?Scm^?1 was achieved for the 95CDP 5WPA composite electrolyte at 170?°C under anhydrous conditions. The ionic conduction was probably induced in the percolated interfacial phase between CDP and WPA. The phenomenon of high ionic conduction differs for the CDP–WPA composite and pure CDP or pure WPA under anhydrous conditions. The newly developed hydrogen interaction between CDP and WPA supports anhydrous proton conduction in the composites.