Effect of the surface temperature on surface morphology, deuterium retention and erosion of EUROFER steel exposed to low-energy, high-flux deuterium plasma

摘要

Highlights ? Strong temperature effect on surface morphology of EUROFER by deuterium plasma exposure. ? Two thermal activation energy (0.2 and 1.3eV) determined for morphology formation. ? Surface structures are decorated with tungsten (enrichment). Abstract Samples of EUFROFER, a reduced activation ferritic martensitic steel, were exposed in the linear plasma device Pilot-PSI to a deuterium (D) plasma with incident ion energy of ～40eV and incident D flux of 2–6×10 23 D/m 2 s to fluences up to 10 27 D/m 2 at surface temperatures ranging from 400K to 950K. The main focus of the study lays on the surface morphology changes dependent on the surface temperature and the surface composition evolution, e.g., the enrichment in tungsten; but also the erosion and the D retention are studied. The created surface morphology varies strongly with surface temperature from needle-like to corral-like structures. The visible lateral length scale of the formed structures is in the range of tens of nanometres to above 1μm and exhibits two thermal activated regimes below and above ～770K with activation energies of 0.2eV and 1.3eV, respectively. The lateral variation of the enrichment of heavy elements on the surface is correlated to this surface morphology at least in the high temperature regime, independent of the origin of the enrichment (intrinsic from the sample or deposited by the plasma). Also the erosion exhibits temperature dependence at least above ～770K as well as a fluence dependence. The amount of deuterium retained in the top 500nm is almost independent of the exposure temperature and is of the order of 10 18 D/m 2 , which would correspond to a sub-monolayer D coverage on the surface. The retained D in the volume summing up over the complete samples exceeds the D retained close to the surface by one order of magnitude.