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首页> 外文期刊>Materials science-Poland: An interdisciplinary journal of physics, chemistry and technology of materials >Mechanical and structural properties of titanium dioxide deposited by innovative magnetron sputtering process
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Mechanical and structural properties of titanium dioxide deposited by innovative magnetron sputtering process

机译:创新的磁控溅射工艺沉积的二氧化钛的机械和结构性能

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摘要

Titanium dioxide thin films were prepared using two types of magnetron sputtering processes: conventional and with modulated plasma. The films were deposited on SiO2 and Si substrates. X-ray diffraction measurements of prepared coatings revealed that the films prepared using both methods were nanocrystalline. However, the coatings deposited using conventional magnetron sputtering had anatase structure, while application of sputtering with modulated plasma made possible to obtain films with rutile phase. Investigations performed with the aid of scanning electron microscope showed significant difference in the surface morphology as well as the microstructure at the thin film cross-sections. The mechanical properties of the obtained coatings were determined on the basis of nanoindentation and abrasion resistance tests. The hardness was much higher for the films with the rutile structure, while the scratch resistance was similar in both cases. Optical properties were evaluated on the basis of transmittance measurements and showed that both coatings were well transparent in a visible wavelength range. Refractive index and extinction coefficient were higher for TiO2 with rutile structure.
机译:使用两种类型的磁控溅射工艺制备二氧化钛薄膜:常规工艺和调制等离子体。将膜沉积在SiO 2和Si衬底上。制备的涂层的X射线衍射测量表明,用两种方法制备的膜都是纳米晶体。然而,使用常规磁控溅射沉积的涂层具有锐钛矿结构,而施加具有调制等离子体的溅射使得可以获得具有金红石相的膜成为可能。借助于扫描电子显微镜进行的研究表明,在薄膜横截面的表面形态以及微观结构上存在显着差异。根据纳米压痕和耐磨性测试确定获得的涂层的机械性能。具有金红石结构的膜的硬度高得多,而两种情况下的耐划伤性都相似。在透射率测量的基础上评估了光学性能,结果表明两种涂层在可见光波长范围内均具有良好的透明性。金红石型TiO2的折射率和消光系数较高。

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