Influence of Obtaining Conditions on Kinetics of the Initial Sintering Stage of Zirconia Nanopowders

摘要

The present paper is devoted to the problem of sintering ceramics based on yttria-stabilized zirconia (Y-TZP). In this paper, we studied the effect of two obtaining methods (co-precipitation and technical hydrolysis) on sintering kinetics of Y-TZP nanopowders. We used the constant rate of heating (CRH) method at different heating rates for determining the sintering mechanisms. The basic mechanism and activation energy ( Q ) of diffusion at the initial sintering stage were estimated using the sintering rate equations that are applicable to the CRH data. We found that nanopowder 3Y-TZP produced by the co-precipitation method (DIPE) was sintered according to the volume diffusion mechanism ( n ?=?1/2) and nanopowder TZ-3Y (TOSOH) produced by the technical hydrolysis was sintered according to the grain boundary diffusion mechanism ( n ?=?1/3).