(2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol

Baldur F?hlisch; Günter Kreiselmeier; Stefan Menner

首页> 外文期刊>Molbank >(2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol

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(2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol

机译：（2endo）-2-氯-4,4-二甲基-8-氧杂双环[3.2.1] oct-6-en-3-one（2）和（2endo）-2-氯-1,4,4-三甲基-8-氧杂双环[3.2.1] oct-6-en-3-one（3）通过[4 + 3]环加成由1,3-二氯-3-甲基丁二-2-酮生成的羟基烯丙基中间体2， 2,2-三氟乙醇

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《Molbank》 |2005年第2期|共页
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Baldur F?hlisch; Günter Kreiselmeier; Stefan Menner;
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1. (2endo)-2-Chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one [J] . Baldur F?hlisch, Jutta Oexle, Michael Buchinger Molbank . 2005,第2期

机译：（2endo）-2-氯-1,4,4-三甲基-8-氧杂双环[3.2.1] oct-6-en-3-one
2. Use of the p-Tolylsulfinyl Group as a Chiral Inductor in Stereoselective [4+3] Cycloaddition Reactions: Preparation of Enantiopure Polysubstituted 8-Oxabicyclo[3.2.1]oct-6-en-3-one Systems Having up to Five Stereocenters [J] . ángel M. Monta?a, Pedro M. Grima, Consuelo Batalla, European journal of organic chemistry . 2014,第13期

机译：对甲苯基亚磺酰基在立体选择性[4 + 3]环加成反应中用作手性电感器：对映体多取代的8-Oxabicyclocyclo [3.2.1] oct-6-en-3-one系统的制备，具有多达五个立体中心
3. Formation and ring-opening of 8-oxabicyclo[3.2.1]oct-6-en-3-ones from (4+3)-cycloaddition of furan and chlorocyclopentanone derivatives [J] . Gao X., Harmata M. Tetrahedron . 2013,第36期

机译：呋喃和氯代环戊酮衍生物的（4 + 3）-环加成反应生成8-氧杂双环[3.2.1] oct-6-en-3-ones和开环
4. (2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol [O] . Baldur Föhlisch, Stefan Menner, Günter Kreiselmeier 2005

机译：（2endo）-2-氯-4,4-二甲基-8-氧杂双环[3.2.1] oct-6-en-3-one（2）和（2endo）-2-氯-1,4,4-三甲基-8-氧杂双环[3.2.1] oct-6-en-3-one（3）通过[4 + 3]环加成由1,3-二氯-3-甲基丁二-2-酮在2中生成的氧基烯丙基中间体2,2-三氟乙醇

(2endo)-2-Chloro-4,4-dimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (2) and (2endo)-2-chloro-1,4,4-trimethyl-8-oxabicyclo[3.2.1]oct-6-en-3-one (3) via [4+3] cycloaddition of an oxyallyl intermediate generated from 1,3-dichloro-3-methylbutan-2-one in 2,2,2-trifluoroethanol

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