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The Electrochemical Behavior of the NiTi Alloy in Different Simulated Body Fluids

机译:NiTi合金在不同模拟体液中的电化学行为

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In order to improve the NiTi alloy biocompatibility, surface treatments become very important. Nevertheless, researchers use different solutions to simulate the body fluids in electrochemical assays, and the correlation between the obtained results is difficult and might not even be possible. The present paper evaluated the electrochemical behavior of polished NiTi surfaces exposed to different simulated body fluid solutions: Hanks solution, Hanks’ balanced salt (HBSS) solution, saline body fluid (SBF) solution, and Ringer solution. The electrochemical behavior of NiTi was evaluated by open circuit potential (OCP) and cyclic voltammetry tests. The surfaces of the samples were also characterized by scanning electron microscopy, which was performed after the electrochemical tests. The results demonstrated that the NiTi alloy shows the same corrosion mechanism (pitting) in all simulated body fluids that were studied. However, the corrosion potential changes for each electrolyte, being HBSS, SBF and Ringer the most corrosive solutions. Furthermore, the Hanks and HBSS solutions demonstrated good reproducibility of the electochemical results. Considering that the HBSS represents an extreme environment, this solution seems to be the most indicated to study the corrosion behavior of NiTi treated surfaces.
机译:为了提高NiTi合金的生物相容性,表面处理变得非常重要。然而,研究人员在电化学测定中使用了不同的溶液来模拟体液,并且所获得的结果之间的关联是困难的,甚至是不可能的。本文评估了暴露在不同模拟体液溶液中的抛光NiTi表面的电化学行为:汉克斯溶液,汉克斯平衡盐(HBSS)溶液,生理盐水(SBF)溶液和林格溶液。 NiTi的电化学行为通过开路电势(OCP)和循环伏安法测试进行了评估。样品的表面也通过在电化学测试后进行的扫描电子显微镜表征。结果表明,在研究的所有模拟体液中,NiTi合金均显示出相同的腐蚀机理(点蚀)。但是,每种电解液的腐蚀电位都会发生变化,其中腐蚀性最高的是HBSS,SBF和Ringer。此外,Hanks和HBSS解决方案证明了电化学结果具有良好的可重复性。考虑到HBSS代表了一种极端的环境,该解决方案似乎是研究NiTi处理过的表面的腐蚀行为的最有效方法。

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