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High-temperature oxidation of sheath materials using mineral-insulated cables for a simulated severe accident

机译:使用矿物绝缘电缆对护套材料进行高温氧化,以模拟严重事故

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In-pile instrumentation systems in present-day light water reactors (LWR) are indispensable to monitor all situations during reactor operation and reactor shut down. However, the systems did not work sufficiently well in situations like the severe accident (SA) at the Fukushima Dai-ichi nuclear power station. Thus, it is necessary to develop monitoring systems for the prevention of injuries in the event of an SA. Mineral-insulated (MI) cables with radiation and heat resistance are exposed to a mixture gas including nitrogen, oxygen, hydrogen, water vapor, and fission products at high temperature under SA conditions. In this study, corrosion tests under the simulated SA conditions (air, air/H_(2)O, and I_(2)/CO/O_(2)/H_(2)O) for temperatures up to 1015°C were performed for candidate sheath materials of type 316 stainless steel (316SS) and nickel-based alloy (NCF600). As a result, a uniform oxide film was formed on the surface of both the 316SS and NCF600 specimens in the air or air/H_(2)O environments from 720°C to 1015°C, and the fracture time of the MI cable was evaluated by the degree of corrosion and the parabolic law. Conversely, when the gas mixture environment contained I_(2), each surface of the specimen showed complicated corrosion behavior that caused not only local corrosion but also the formation of a uniform oxide film at 800°C.
机译:当前的轻水反应堆(LWR)中的桩内仪表系统对于监测反应堆运行和反应堆关闭期间的所有情况都是必不可少的。但是,该系统在福岛第一核电站的严重事故(SA)等情况下无法正常运行。因此,有必要开发用于在发生SA时防止伤害的监视系统。具有抗辐射和耐热性的矿物绝缘(MI)电缆在SA条件下于高温下暴露于混合气体,包括氮气,氧气,氢气,水蒸气和裂变产物。在这项研究中,对温度高达1015°C的模拟SA条件(空气,空气/ H_(2)O和I_(2)/ CO / O_(2)/ H_(2)O)进行了腐蚀测试用于316不锈钢(316SS)和镍基合金(NCF600)的候选护套材料。结果,在720°C至1015°C的空气或空气/ H_(2)O环境中,在316SS和NCF600试样的表面上均形成了均匀的氧化膜,MI电缆的断裂时间为通过腐蚀程度和抛物线定律评估。相反,当混合气体环境中含有I_(2)时,试样的每个表面都表现出复杂的腐蚀行为,不仅导致局部腐蚀,而且在800°C下形成均匀的氧化膜。

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