Slow Magnetic Relaxation in Unprecedented Mono-Dimensional Coordination Polymer of Ytterbium Involving Tetrathiafulvalene-Dicarboxylate Linker

摘要

A one-dimensional compound has been constructed through a Yb III ion and bridging redox-active deprotonated 4,5-bis(carboxylic)-4′,5′-methyldithiotetrathiafulvene. This polymer displays slow magnetic relaxation due to the planar magnetic anisotropy of the Yb III , which has been experimentally determined.