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STUDY ON THE KINETICS OF BIOMASS BLENDS DEWATERING AS A STAGE OF THERMAL DEGRADATION

机译:热降解阶段生物质共混物的动力学研究

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Solid biomass co-combustion with coal in industrial furnaces, including those of power plants, looks promising in terms of fuel base diversification and also presents a way to reduce significantly the emission of air harmful pollutants, particularly carbon dioxide. CO 2 resultingfrom biomass burning is environmentally neutral, since the same amount of carbon dioxide will be consumed at the next cycle of biomass photosynthesis. In case of the Ukrainian low reactive anthracite schtib used in such technology, the radical differences in the kinetic characteristics of co-fired fuels become critical issues. A significant difference in the attainable degree of fuel milling fineness due to the prohibitively high expense for solid biomass milling makes the problem more complicated. The values of biomass particle fineness are approximately 5…15 mm; whereas the fineness of pulverized coal reaches as low as 30...50mkm. The moisture and volatiles content for the fuel mentioned also differ noticeably. Therefore, the stages of these fuels burn out will be extremely complex in terms of various time scales of subsequent stages and their positioning in the furnace. The case becomes even more aggravated insofar the kinetic characteristic of the stages of biomass combustion arenot known yet in details. The present work is dedicated to the research into the kinetics of biomass blends demoisturizationand aimed at the deriving of the Arrhenius type equations, allowing to develop submodels of the demoisturization as an individual stage of biomass burn out for 3-D models.
机译:在包括发电厂在内的工业窑炉中,固体生物质与煤炭的共燃烧在燃料基础多样化方面看起来很有希望,并且还提出了一种显着减少空气中有害污染物,特别是二氧化碳排放的方法。由生物质燃烧产生的CO 2在环境上是中性的,因为在生物质光合作用的下一周期将消耗相同量的二氧化碳。在这种技术中使用乌克兰低反应性无烟煤schtib的情况下,共燃燃料动力学特性的根本差异成为关键问题。由于用于固体生物质研磨的高得惊人的花费,在可获得的燃料研磨细度上的显着差异使问题更加复杂。生物质颗粒细度的值约为5…15 mm;而煤粉的细度可低至30 ... 50mkm。提到的燃料的水分和挥发物含量也明显不同。因此,就后续阶段的各种时间尺度及其在炉中的位置而言,这些燃料的燃烧阶段将极为复杂。就生物质燃烧阶段的动力学特性而言,这种情况甚至变得更加严重,目前尚不清楚。目前的工作致力于生物质混合物去离子动力学,并旨在推导Arrhenius型方程,允许开发去离子化的子模型,作为3-D模型中生物量消耗的单个阶段。

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