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Comparative Study on Methods for Preparation of Gold Nanoparticles

机译:金纳米粒子制备方法的比较研究

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The gold nanoparticles were prepared in many methods, differed in reducing and dispersion agents and stability. The first solution was prepared by using potassium bitartrate as reducing agent and Polyethylene glycol as a dispersion factor. We got a solution of colloid gold with wine-red color that has been measured the particle size; it was between 50 - 200 nanometers. The second gold colloidal solution was prepared by using sodium citrate as a reducing agent and without adding a dispersion agent, the color of the final solution is dark grey, but this solution did not remain stable, deposition happened quickly and crystals separated from the solution. The third one was prepared by using sodium citrate as a reducing agent and the solution was heated to a certain temperature, and the color of the solution became dark red after several minutes. Either the fourth method has been prepared gold colloid solution by using potassium bitartrate as a reductant for the gold ion. We have noted that no reaction under normal conditions, while the reaction by heating the solution to high temperature, and when added poly vinyl pyrrolidone will lead to a solution of colloild gold with dark purple-red color and stable under normal conditions for a long time. We measured the particles size in this experiment; it was less than 100 nanometers. We conclude from the above that all the reducing agent needs to appropriate conditions to complete the process of reduction of gold ion, and to get the nano gold particles, therefore; these particles in the colloid solution need to dispersion factor to the survival of the particles widespread so that the solutions with certain concentrations of poly vinyl pyrrolidone can be proven in the process of stability of the gold colloid solution.
机译:金纳米颗粒的制备方法很多,还原剂和分散剂及稳定性不同。通过使用酒石酸氢钾作为还原剂和聚乙二醇作为分散因子来制备第一溶液。我们得到了一种具有酒红色的胶体金溶液,该溶液已经过粒度测定。它在50-200纳米之间。通过使用柠檬酸钠作为还原剂并且不添加分散剂来制备第二种金胶体溶液,最终溶液的颜色为深灰色,但是该溶液不能保持稳定,快速发生沉积并且从溶液中分离出晶体。通过使用柠檬酸钠作为还原剂制备第三种溶液,并将溶液加热至一定温度,并且在几分钟后溶液的颜色变为深红色。第四种方法都已经通过使用酒石酸氢钾作为金离子的还原剂来制备金胶体溶液。我们已经注意到,在正常条件下没有反应,而通过将溶液加热到高温进行反应,以及加入聚乙烯吡咯烷酮时会导致溶液溶出金黄色,深紫色红色,并且在正常条件下稳定很长时间。 。我们在该实验中测量了颗粒大小;它小于100纳米。由以上我们得出结论,所有还原剂都需要在适当的条件下完成金离子的还原过程,从而获得纳米金颗粒。胶体溶液中的这些颗粒需要分散因子才能使广泛存在的颗粒存活,从而可以在金胶体溶液的稳定性过程中证明具有一定浓度的聚乙烯吡咯烷酮的溶液。

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