首页> 外文期刊>IUCrData >11-[Bis(tri-methyl-sil-yl)amino]-2,4-bis--(tri-methyl-sil-yl)-7,8,9,10-tetra-hydro-6H-cyclo-hepta-[1,2-b]quinoline
【24h】

11-[Bis(tri-methyl-sil-yl)amino]-2,4-bis--(tri-methyl-sil-yl)-7,8,9,10-tetra-hydro-6H-cyclo-hepta-[1,2-b]quinoline

机译:11- [双(三甲基硅基)氨基] -2,4-双-(三甲基硅基)-7,8,9,10-四氢-6H-环庚-[1,2-b]喹啉

获取原文
       

摘要

In the title compound, C26H48N2Si4, the cycloheptane ring adopts a chair conformation, while the quinolinyl ring system is almost planar [maximum deviation = 0.040 (3) A? for one of the C atoms carrying a Me3Si group]. In the crystal, in the absence of classical hydrogen bonding, the packing is dominated by van der Waals forces. One of the N-bound trimethylsilyl groups is disordered by rotation about the C—SiMe3 bond, and was modelled over two sets of sites in the ratio 0.873 (8):0.127 (8).
机译:在标题化合物C26H48N2Si4中,环庚烷环采用椅子构象,而喹啉基环系统几乎是平面的[最大偏差= 0.040(3)带有Me 3 Si基的C原子之一]。在晶体中,在没有经典氢键的情况下,填充物受到范德华力的支配。 N-键合的三甲基甲硅烷基基团中的一个由于绕C-SiMe3键旋转而无序,并在两组位点上以0.873(8):0.127(8)的比例建模。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号