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Physical Properties of Soy-Phosphate Polyol-Based Rigid Polyurethane Foams

机译:大豆磷酸酯多元醇硬质聚氨酯泡沫的物理性能

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Water-blown rigid polyurethane (PU) foams were made from 0–50% soy-phosphate polyol (SPP) and 2–4% water as the blowing agent. The mechanical and thermal properties of these SPP-based PU foams (SPP PU foams) were investigated. SPP PU foams with higher water content had greater volume, lower density, and compressive strength. SPP PU foams with 3% water content and 20% SPP had the lowest thermal conductivity. The thermal conductivity of SPP PU foams decreased and then increased with increasing SPP percentage, resulting from the combined effects of thermal properties of the gas and solid polymer phases. Higher isocyanate density led to higher compressive strength. At the same isocyanate index, the compressive strength of some 20% SPP foams was close or similar to the control foams made from VORANOL 490.
机译:水发泡硬质聚氨酯(PU)泡沫是由0-50%的大豆磷酸酯多元醇(SPP)和2-4%的水作为发泡剂制成的。研究了这些基于SPP的PU泡沫(SPP PU泡沫)的机械和热性能。含水量较高的SPP PU泡沫具有较大的体积,较低的密度和抗压强度。水含量为3%,SPP为20%的SPP PU泡沫的导热系数最低。 SPP PU泡沫的热导率随SPP百分比的增加而下降,然后增加,这是由于气相和固态聚合物相的热性能的综合影响所致。较高的异氰酸酯密度导致较高的抗压强度。在异氰酸酯指数相同的情况下,约20%SPP泡沫的抗压强度与VORANOL 490制成的控制泡沫接近或相似。

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