Process analysis of electroless copper plating for AB5-type hydrogen storage alloy using support vector regression

摘要

Surface modification is an effective method to improve the electrochemical property of hydrogen storage alloy. In order to investigate theinfluence ofprocess factors of electroless copper (Cu) platingfor AB5-type hydrogen storage alloy on Cu coating mass, a novel modeling approach, support vector regression (SVR) combined with particle swarm optimization (PSO), wasproposedto construct a mathematical model for prediction of the mass changes of Cu coating over the AB5hydrogen storage alloy surface based on three factors, including temperature, pH value and Ni2+concentration. The modeling accuracy and reliability of the created SVR model are validated through leave-one-out cross validation (LOOCV), and compared with those of a second-order polynomial model. The results show that the predicted errors by SVR-LOOCV models are all smaller than those achieved bythesecond-order polynomial model. The SVR model is further applied to predict the process parameters for themaximumCu coating mass. These studies suggest that SVR can be used as an effective methodology to assist the design of experiment, and is helpful topreciselycontrol thecoating massviafine adjustment of theprocess parameters.