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Growth and Characterization of a Non Linear Optical Crystal - Bis Thiourea Cadmium Chloride

机译:非线性光学晶体双硫脲氯化镉的生长与表征

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摘要

Bulk crystal of bis thiourea cadmium chloride (BTCC) was grown by the solvent evaporation method and slow cooling method. The crystal structure was confirmed using single crystal XRD studies. The presence of thiourea in the complex and the metal-sulphur bond has been confirmed from the FTIR and Raman spectra. The thermal analysis shows the good stability of the crystal up to 211oC. The crystal was found to show an SHG efficiency of twice that of KDP. The surface analysis of the grown crystal was studied using AFM studies and the results are discussed in detail.
机译:通过溶剂蒸发法和缓慢冷却法生长双硫脲氯化镉(BTCC)的块状晶体。使用单晶XRD研究证实了晶体结构。从FTIR和拉曼光谱已经证实了配合物中和金属-硫键中硫脲的存在。热分析表明,晶体在高达211oC的温度下具有良好的稳定性。发现该晶体显示出SHG效率是KDP的两倍。使用AFM研究了生长晶体的表面分析,并对结果进行了详细讨论。

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