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TRANSFORMATION KINETICS FOR NUCLEATION ON RANDOM PLANES AND LINES

机译:随机平面和直线上成核的变换动力学

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Birth and growth processes are known in materials science as nucleation and growth processes. In crystalline materials nucleation almost always takes place in an internal crystalline defect. These defects are classified according to their dimensionality: point, line or planar defects. Therefore, investigating nucleation on sets of dimensionality lower than the set in which the transformation takes place is of paramount importance. Cahn (1956) in a classical work derived expressions for transformation kinetics when nucleation took place on random planes and on random straight lines. He used these expressions to describe nucleation in polycrystalline materials. He considered that nucleation on grain faces could be treated as nucleation on random planes and, likewise, nucleation on grain edges could be treated as nucleation on random lines. The present work revisits and generalizes Cahn’s treatment of nucleation on planes and lines. First a general expression for the case of nucleation on lower dimensional sets is obtained. After that general expressions for nucleation on random planes and random lines are given. This paper provides the mathematical basis for the development of more specific expressions to be used in practical applications. Although this work has been done bearing applications to materials science in mind the results obtained here may be applied to birth and growth processes in any field of science.
机译:出生和成长过程在材料科学中被称为成核和成长过程。在晶体材料中,成核几乎总是发生在内部晶体缺陷中。这些缺陷根据其尺寸进行分类:点,线或平面缺陷。因此,研究比发生变换的维数集低的维数集的成核是至关重要的。 Cahn(1956)在经典著作中推导了成核发生在随机平面和随机直线上时的转变动力学表达式。他使用这些表达式来描述多晶材料中的形核。他认为晶粒表面的形核可被视为随机平面上的形核,同样,晶粒边缘的形核可被视为随机线上的形核。本工作回顾并概括了卡恩对飞机和直线成核的处理。首先,获得了在低维集合上成核的一般表达式。之后,给出了在随机平面和随机线上成核的一般表达式。本文为开发在实际应用中使用的更具体的表达式提供了数学基础。尽管完成这项工作时要牢记在材料科学中的应用,但此处获得的结果可能会应用于任何科学领域的诞生和成长过程。

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