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Elemental analysis of commercially available rice samples in Malaysia by using ICP-MS and SEM-EDX

机译:使用ICP-MS和SEM-EDX对马来西亚市售大米样品进行元素分析

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摘要

Rice is the staple food in Malaysia. There are limited literature about study on the elemental levels and observation on ultrastructure of commercially available white rice and brown rice in Malaysia. Therefore, the objectives of this study were to determine the concentration of elements in three uncooked long rice grain, i.e. two brown rice and one white rice varieties that are commercially available in Malaysia using inductively coupled plasma mass spectrometry (ICP-MS) and compare the structure and elements of uncooked and cooked rice grain using Scanning Electron Microscopy-Energy Dispersive X-Ray Spectroscopy (SEM-EDX). The ICP-MS results of the three uncooked rice grains showed high concentration of copper, manganese and zinc, followed with potassium, magnesium and calcium. Besides, the element contaminant such as plumbum, antimony and cadmium in the rice grains were under Malaysian permissible limit (Malaysian Food Act, 1983) and international standard (FAO/WHO, 2002). Arsenic was below Malaysian permissible limit but higher than safe limit by international standard. Silicon was observed in brown rice after viewed by using SEM-EDX. Besides, brown rice showed higher concentration of elements than white rice.
机译:大米是马来西亚的主食。在马来西亚,有关市售白米和糙米的元素水平和超微结构观察的文献很少。因此,本研究的目的是使用感应耦合等离子体质谱法(ICP-MS)确定在马来西亚可商购的三种未煮过的长米粒中的元素浓度,即两种糙米和一种白米品种,并比较扫描电子显微镜-能量色散X射线光谱法(SEM-EDX)分析未煮熟米粒的结构和元素。三种未煮过的米粒的ICP-MS结果表明,铜,锰和锌的浓度很高,其次是钾,镁和钙。此外,米粒中的铅,锑和镉等元素污染物也处于马来西亚允许的限值(马来西亚食品法,1983年)和国际标准(粮农组织/世界卫生组织,2002年)之内。砷低于马来西亚允许的限值,但高于国际标准的安全限值。使用SEM-EDX观察后,在糙米中观察到硅。此外,糙米比白米显示出更高的元素浓度。

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