Toward resolving the budget discrepancy of ozone-depleting carbon tetrachloride?(CClsub4/sub): an analysis of top-down emissions from China

摘要

Carbon tetrachloride?(CClsub4/sub) is a first-generation ozone-depleting substance, and its emissive use and production were globally banned by the Montreal Protocol with a 2010?phase-out; however, production and consumption for non-dispersive use as a chemical feedstock and as a process agent are still allowed. This study uses the high frequency and magnitude of CClsub4/sub pollution events from an 8-year real-time atmospheric measurement record obtained at Gosan station (a regional background monitoring site in East Asia) to present evidence of significant unreported emissions of CClsub4/sub. Top-down emissions of CClsub4/sub amounting to 23.6±7.1 Gg yrsup?1/sup from?2011 to?2015 are estimated for China, in contrast to the most recently reported, post-2010, Chinese bottom-up emissions of 4.3–5.2 Gg yrsup?1/sup. The missing emissions (?～?19 Gg yrsup?1/sup) for China contribute to approximately 54 % of global CClsub4/sub emissions. It is also shown that 89?%?±?6 % of CClsub4/sub enhancements observed at Gosan are related to CClsub4/sub emissions from the production of CHsub3/subCl, CHsub2/subClsub2/sub, CHClsub3/sub and Csub2/subClsub4/sub and its usage as a feedstock and process agent in chemical manufacturing industries. Specific sources and processes are identified using statistical methods, and it is considered highly unlikely that CClsub4/sub is emitted by dispersive uses such as old landfills, contaminated soils and solvent usage. It is thus crucial to implement technical improvements and better regulation strategies to reduce evaporative losses of CClsub4/sub occurring at the factory and/or process levels.