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Preparation and photo catalytic activity of Fe3+- doped TiO2nanoparticles

机译:Fe3 +掺杂TiO2纳米粒子的制备及光催化活性

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Pure TiO2 exhibits low photocatalytic property due to rapid recombination of photo-activated electrons and holes. Fe3+ was considered to dope into TiO2 photo catalyst in order to enhance the photocatalytic property. The Fe3+ doped TiO2 nanoparticles were prepared by sol-gel method and calcined at 400°C for 2h. The synthesized powders were characterized by Uv-Vis, XRD, SEM, FT-IR and photocatalytic activity was determined by means of degradation of methyl orange solution under UV light irradiation. Fe3+ doping into TiO2 has an effect on inhibition of anatase crystal growth, led to the enlargement of the composite specific surface area. Therefore, the photocatalytic activity of Fe3+ doped TiO2 composite in proper concentration was greater than those of pure TiO2 and 0.5 mol% Fe3+ doping exhibited the highest photocatalytic activity.
机译:由于光活化电子和空穴的快速复合,纯TiO2表现出较低的光催化性能。为了增强光催化性能,考虑将Fe3 +掺入TiO2光催化剂中。采用溶胶-凝胶法制备了Fe3 +掺杂的TiO2纳米粒子,并在400℃下煅烧2h。通过Uv-Vis,XRD,SEM,FT-IR对合成的粉末进行了表征,并通过甲基橙溶液在紫外光照射下的降解来测定其光催化活性。 Fe3 +掺杂到TiO2中会抑制锐钛矿晶体的生长,从而导致复合比表面积的增大。因此,适当浓度的Fe3 +掺杂的TiO2复合材料的光催化活性要大于纯TiO2,并且0.5 mol%的Fe3 +掺杂表现出最高的光催化活性。

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