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Heterocyclic Organic Derivative as Corrosion Inhibitor for Mild Steel in 1 N HCl

机译:杂环有机衍生物作为1 N HCl中低碳钢的腐蚀抑制剂

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The inhibition effect of heterocyclic organic derivative viz., 2-(Benzothiazol-2-ylsulfanyl)-1-(5- methyl-thiazol-2-ylamino)-ethanol (BMTE) was evaluated against mild steel corrosion in 1 N HCl solutions using conventional weight loss method, potentiodynamic polarization, linear polarization and electrochemical impedance spectroscopy. The results of weight loss method have proved that BMTE was efficient corrosion inhibitor. Electrochemical polarizations such as Tafel Intercept and Linear Polarization Resistance revealed the mixed mode of inhibition. The results of electrochemical impedance spectroscopy have shown the changes in the impedance parameters like charge transfer resistance and double layer capacitance to confirm the strong adsorption on the mild steel surface. The increase in the value of inhibition efficiency was due to the adsorption of the molecules evaluated leading to the formation of a protective layer on the surface of mild steel. The inhibition action of these compounds was, assumed to occur via adsorption on the steel surface through the active centres contained in the molecules.
机译:使用1 N HCl溶液评估了杂环有机衍生物即2-(苯并噻唑-2-基硫烷基)-1-(5-甲基-噻唑-2-基氨基)-乙醇(BMTE)的缓蚀性能常规的减重方法,电位动力学极化,线性极化和电化学阻抗谱。失重法的结果证明,BMTE是有效的缓蚀剂。电化学极化(例如Tafel拦截和线性极化电阻)显示了混合的抑制模式。电化学阻抗谱的结果表明,阻抗参数如电荷转移电阻和双层电容的变化证实了在低碳钢表面上的强烈吸附。抑制效率值的提高是由于所评估分子的吸附导致在低碳钢表面形成保护层。假定这些化合物的抑制作用是通过分子中所含的活性中心在钢表面上的吸附而发生的。

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