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Physicochemical and Spectroscopic Characterization of Biofield Treated Triphenyl Phosphate

机译:经生物处理的磷酸三苯酯的理化和光谱表征

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Triphenyl phosphate (TPP) is a triester of phosphoric acid and phenol. It is commonly used as a fire-retarding agent and plasticizer for nitrocellulose and cellulose acetate. The present study was an attempt to evaluate the impact of biofield treatment on physicochemical and spectroscopic properties of TPP. The study was carried out in two groups ii.e./i control and treatment. The treatment group was subjected to Mr. Trivedi’s biofield treatment. The control and treated samples of TPP were characterized using X-ray diffraction (XRD), differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR), and ultraviolet-visible (UV-Vis) spectroscopy. XRD study revealed the decrease in crystallite size (6.13%) of treated TPP that might be due to presence of strains and increase in atomic displacement from their ideal lattice positions as compared to control sample. DSC thermogram of treated TPP showed the increase in melting temperature (1.5%) and latent heat of fusion (66.34%) with respect to control. TGA analysis showed the loss in weight by 66.79% in control and 47.96% in treated sample. This reduction in percent weight loss suggests the increase of thermal stability in treated sample as compared to control. FT-IR and UV spectroscopic results did not show the alteration in the wavenumber and wavelength of FT-IR and UV spectra, respectively in treated TPP with respect to control. Altogether, the XRD and DSC/TGA results suggest that biofield treatment has the impact on physical and thermal properties of treated TPP.
机译:磷酸三苯酯(TPP)是磷酸和苯酚的三酯。通常用作硝酸纤维素和醋酸纤维素的阻燃剂和增塑剂。本研究试图评估生物场处理对TPP的理化性质和光谱性质的影响。该研究分为两组,即对照组和治疗组。治疗组接受了特里维迪先生的生物野外治疗。使用X射线衍射(XRD),差示扫描量热法(DSC),热重分析(TGA),傅里叶变换红外(FT-IR)和紫外可见(UV-Vis)光谱对TPP的对照和处理样品进行表征。 XRD研究表明,与对照样品相比,处理过的TPP的微晶尺寸减少了(6.13%),这可能是由于存在应变以及原子从理想晶格位置偏离而增加。经处理的TPP的DSC热分析图显示,相对于对照,其熔融温度(1.5%)和熔融潜热(66.34%)有所增加。 TGA分析显示,对照中的重量损失为66.79%,处理样品中的重量损失为47.96%。重量损失百分比的降低表明与对照相比,处理后样品的热稳定性提高。 FT-IR和UV光谱结果未显示相对于对照,处理过的TPP中FT-IR和UV光谱的波数和波长分别发生了变化。总之,XRD和DSC / TGA结果表明,生物田处理对处理过的TPP的物理和热学性质有影响。

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