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Rice Husk ash as Flatting Extender in Cellulose Matt Paint

机译:稻壳灰作为纤维素哑光涂料中的展平剂

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The high silica content of rice husk ash (RHA) promotes its attractiveness as an abundant, cheap and renewable resource for various industrial applications such as surface coatings formulation. This study investigated the applicability of rice husk ash (RHA) as a flatting extender in cellulose matt paint and compared its flatting effect with those of two commercial extenders; fumed silica (the standard flatting agent) and silica flour. RHA was obtained by controlled incineration of rice husks at a temperature of 6500C and duration of 4hrs. The granular ash was then ground and sieved to obtain RHA flour with a particle size of ~32microns used in the formulation of the cellulose paints. Cellulose paint produced with fumed silica of 20μm-particle size was the reference standard while a sample produced with 0% extender served as the Control. The gloss values of the dry films of the paints were measured with a gloss meter at 200 angle of reflectance and their matt values calculated from their gloss values. The results showed that all three extenders substantially reduced the gloss levels of the cellulose paint samples with a resultant corresponding increase in their matt values. Although the flatting agents displayed varied degrees of flatting effect, their matt values were all over 100% higher than that of the Control. Fumed silica was highest in flatting performance, followed closely by RHA while silica flour ranked third. This trend was evident in the matt values (%) of 98.2±0.00, 94.7±0.06 and 86.9±0.11 obtained for cellulose matt paints produced with fumed silica, RHA and silica flour respectively. The Control had the lowest matt value of 42.9% showing its glossy nature due to the absence of a flatting agent.
机译:稻壳灰(RHA)的高二氧化硅含量提高了其吸引力,作为各种工业应用(如表面涂料配方)的丰富,廉价和可再生资源。这项研究调查了稻壳灰(RHA)作为纤维素哑光涂料中的消光剂的适用性,并将其消光效果与两种市售的消光剂进行了比较。气相法二氧化硅(标准消光剂)和二氧化硅粉。 RHA是通过在6500°C的温度和4小时的持续时间内对稻壳进行受控焚烧而获得的。然后将粒状灰分研磨并过筛,以获得粒径约32微米的RHA面粉,用于配制纤维素涂料。以20μm粒度的气相二氧化硅生产的纤维素涂料为参考标准,而增量剂为0%的样品为对照。用光泽计在200°反射角下测量涂料干膜的光泽度值,并由其光泽度值计算出无光泽值。结果表明,所有三种增量剂均显着降低了纤维素涂料样品的光泽度,从而导致其哑光值相应增加。尽管消泡剂表现出不同程度的消泡效果,但其哑光值均比对照值高100%以上。气相法二氧化硅的平整性能最高,紧随其后的是RHA,而二氧化硅粉则排名第三。这种趋势在用气相二氧化硅,RHA和二氧化硅粉分别生产的纤维素哑光涂料获得的哑光值(%)为98.2±0.00、94.7±0.06和86.9±0.11时很明显。对照品的最低哑光值为42.9%,由于没有消光剂,显示了光泽特性。

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