Nanoengineering to Achieve High Sodium Storage: A Case Study of Carbon Coated Hierarchical Nanoporous TiO 2 Microfibers

摘要

Abstract Nanoengineering of electrode materials can directly facilitate sodium ion accessibility and transport, thus enhancing electrochemical performance in sodium ion batteries. Here, highly sodium-accessible carbon coated nanoporous TiO 2 microfibers have been synthesised via the facile electrospinning technique which can deliver an enhanced capacity of ?￠????167 mAh g ?￠????1 after 450 cycles at current density of 50 mA g ?￠????1 and retain a capacity of ?￠????71 mAh g ?￠????1 at the high current rate of 1 A g ?￠????1 . With the benefits of their porous structure, thin TiO 2 inner walls, and the introduction of conductive carbon, the nanoporous TiO 2 /C microfibers exhibit high ion accessibility, fast Na ion transport, and fast electron transport, thereby leading to the excellent Na-storage properties presented here. Nanostructuring is proven to be a fruitful strategy that can alleviate the reliance on materials' intrinsic nature; and the electrospinning technique is versatile and cost-effective for the fabrication of such an effective nanoporous microfiber structure.