Synthesis and spectroscopic properties of β-meso directly linked porphyrin–corrole hybrid compounds

摘要

The preparation of β- meso directly linked porphyrin–corrole hybrids was realized for the first time via an InCl₃-catalyzed condensation reaction of 2-formyl-5,10,15,20-tetraphenylporphyrins with meso -substituted dipyrromethanes. Hybrid compounds have been characterized by 1H NMR, 13C NMR, 2D NMR, UV–vis absorption and fluorescence spectroscopy.