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Optimization of the column studies into the adsorption of basic dye using tartaric acid-treated bagasse

机译:用酒石酸处理的蔗渣对吸附碱性染料的色谱柱研究的优化

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Previous batch studies have shown that acid treated bagasse is a potentially useful adsorbent for treating dye wastewaters. The present paper examines the use of tartaric acid-modified bagasse for the continuous adsorption of methylene blue (MB) dye in columns. The adsorbent was characterized using Fourier transform infrared spectroscopy and scanning electron microscopy. A 2~3 full factorial design analysis was carried out to screen the significant parameters that affecting the adsorption of MB dye onto tartaric acid-modified bagasse, namely initial MB concentration (100-300 mg/L), column bed height (40-80 mm), and feed flow rate (5-15 mL/min). The adsorption process was optimized using response surface methodology -central composite design with the help of Minitab~® 14 software. Maximum decolorization (99.42%) and chemical oxygen demand reduction (88.40%) could be achieved at 200 mg/L inlet MB dye concentration with 78 mm bed height and 3.5 mL/min of feed flow rate. Thomas and Yoon-Nelson models were in good agreement with the experimental results (r~2>0.91).
机译:以前的批处理研究表明,酸处理过的蔗渣是处理染料废水的潜在有用吸附剂。本文研究了酒石酸改性的蔗渣在柱中亚甲基蓝(MB)染料的连续吸附中的应用。使用傅里叶变换红外光谱和扫描电子显微镜对吸附剂进行表征。进行了2〜3次全因子设计分析,筛选出影响MB染料吸附在酒石酸改性蔗渣上的重要参数,即初始MB浓度(100-300 mg / L),柱床高度(40-80) (mm)和进料流速(5-15 mL / min)。借助Minitab〜®14软件,使用响应表面方法-中心复合设计优化了吸附过程。在200 mg / L的入口MB染料浓度,78 mm的床高和3.5 mL / min的进料流速下,可以实现最大的脱色(99.42%)和化学需氧量减少(88.40%)。 Thomas和Yoon-Nelson模型与实验结果吻合良好(r〜2> 0.91)。

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