Solar degradation of malachite green using nickel-doped TiO2 nanocatalysts

摘要

Malachite green (MG) is one of the most used dyes in textile industries. The aim of this research work was to degrade MG, a model dye, using nickel-doped TiO2 nanocatalysts. Nickel-doped TiO2 nanocatalysts were fabricated under mild hydrothermal conditions (p=autogenous, T=100 degrees C, and t=12h). Nickel oxide and n-butylamine were used as dopant and surface modifier, respectively. The samples dried were characterized using powder X-ray diffraction, zeta potential, SEM, and electron diffraction X-ray analysis. The batch experiments of MG degradation were performed under UV light and sunlight irradiation. The effect of operational parameters including nanocatalyst dosage, pH, contact time, initial concentration of dye solution, and light source were investigated systematically. It was found that nickel-doped TiO2 nanocatalysts had better solar degradation efficiency compared with bare TiO2 under both UV light and sunlight irradiation. The optimum solar degradation efficiency for MG dye solution was achieved at pH8, nanocatalyst dosage=1.2g/l, contact time=120min, and initial dye concentration=250mg/l.