Structures and properties of assembled oxidized metal complexes with C_8H_4S_8 and related sulfur-rich dithiolate ligands

摘要

Metal complexes with the C_8H_4S~2- _8 ligand [2-{(45,-ethyleneditio)-1,3-dithiole-2-ylidene}-1,3-dithiole-4,5-dithiolate (2-)] of the types of [M(C_8H_4S_8)_2]~n- [M=Pt(Ⅱ), Au(Ⅲ); n=1,2=], [M(N-N)(C_8H_4S_8)] [M=Pd(Ⅱ), Pt(Ⅱ); N-N=2,2'=bipyridine, etc.], [Sn(C_8H_4S_8)_3]~2-, [PhSn(C_8H_4S_8)_2~-, [M(O) (C_8H_4S_8)_2]~2- [M=V(Ⅳ), Mo(Ⅳ), [Co(η~5-C_5H_5) (C_8H_4S_8)], [M(L)_2(C_8H_4S_8)] [M= Ti(Ⅳ), Zr(Ⅳ), [M(L) (C_8H_4S)8]_2]~- [M=Ti(Ⅳ), Zr(Ⅳ), Hf(Ⅳ); L=5~5-C_5H_5 and η~5-C_5H_5 and η~5-C_5Me_5] and [Fe(η~5-C_5H_5)(CO)_2(L-L)Fe(η~5- C_5H_5)(CO)_2](L=C_3S_5-C_3S_5, C_8H_4S_8=C_8H_4S_8) and metal complexes with realted sulfur-rich dithiolate ligands have been prepared.