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Effectiveness of the mild alkali and dilute polymer modification in controlling the durability of jute fibre in alkaline cement medium

机译:温和的碱和稀聚合物改性对控制黄麻纤维在碱性水泥介质中的耐久性的有效性

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With the aim to improve the durability of natural fibres used as fibre reinforcement in the cement matrix, the combined alkali and polymer modification would be a unique approach. The present investigation deals with the durability performances of the unmodified and combined mild alkali and polymer emulsion modified jute fibres exposed to alkaline medium and cement medium as well. Initially, the jute fibres were modified using mild alkali (0.5% NaOH, 24 h) and dilute polymer emulsion (0.125% carboxylated styrene butadiene rubber (SBR)) sequentially. Afterward, the unmodified and modified jute fibres were then exposed to the saturated lime solution, 0.1 N NaOH solution, and cement paste for 360 days. After periodic exposure in different media, the fibres were removed and tested. Based on the results, it is demonstrated that the combined alkali and polymer modified jute fibre retains 17, 19 and 20% more tensile strength as compared to that of the raw jute fibre after 360 days exposure in saturated lime solution, NaOH solution, and cement paste, respectively. The improved durability of the combined alkali and polymer modified jute appears to be due to the reduction of fibre mineralization by forming a protective coating of polymer on the fibre surface as demonstrated by elemental analysis, FTIR, XRD, NMR, SEM in conjugation with EDS. (C) 2018 Elsevier Ltd. All rights reserved.
机译:为了提高天然纤维在水泥基质中用作纤维增强材料的耐久性,碱和聚合物的组合改性将是一种独特的方法。本研究涉及暴露于碱性介质和水泥介质中的未改性和混合的弱碱和聚合物乳液改性黄麻纤维的耐久性能。最初,先用中性碱(0.5%NaOH,24 h)和稀聚合物乳液(0.125%羧化丁苯橡胶(SBR))对黄麻纤维进行改性。然后,将未改性的和改性的黄麻纤维暴露于饱和石灰溶液,0.1 N NaOH溶液和水泥浆中360天。在不同介质中定期暴露后,将纤维取出并进行测试。根据结果​​,经碱和聚合物改性的黄麻纤维复合材料在饱和石灰溶液,NaOH溶液和水泥中暴露360天后,其抗张强度比原黄麻纤维高17、19和20%。分别粘贴。经碱和聚合物改性的黄麻的改进的耐久性似乎是由于通过在纤维表面上形成聚合物的保护涂层而减少了纤维矿化作用,如元素分析,FTIR,XRD,NMR,SEM与EDS结合所证明的。 (C)2018 Elsevier Ltd.保留所有权利。

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