Photoinduced intramolecular electron transfer and charge separation in zinc phthalocyanine-viologen linked system

摘要

Photoinduced electron transfer and charge separation processes in zinc phthalocya- nine-viologen linked system have been studied and the distance effect of donor/acceptor on electron transfer reaction is discussed. It is indicated that the fluorescence from the zinc phthalocyanine moiety is appreciably quenched and the life-time of singlet excited state is reduced by the pendant viologen. Time-resolved transient absorption spectra measurements show that intramolecular quenching of the triplet state of zinc phthalocyanine by the attached viologen results in charge separation giving reduced viologen radical alive for a rather long period with hundred microsecond duration. The effect of the carbon chain length on the electron transfer rate constant and charge separation efficiency suggests that upon excitation, the zinc phthalocyanine and viologen groups tend to take closer conformation with the increase of the carbon chain examined. The rate constant for the intramolecular electron transfer k_(et) with n = 3 to 10 is in the order of 10~4 s~(-1) and increases.