Synthesis and Crystal Structure of a Puckered Rhombus Grid-like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker

摘要

A new coordination polymer with sulfide moieties, [Co(ptmb)_2]·0.25H_2O (ptmb=4-(4-pyridylthiomethyl)-benzoate), was synthesized by self-assembly of Co(NO_3)_2·6H_2O with Hptmb under solvothermal conditions. X-ray single crystal diffraction study shows that it is a 2D layer structure consisting of puckered rhombus grid with dimensions 1.175 nm x 1.110 nm.