Synthesis and Crystal Structure of a Puckered Rhombus Grid-like Coordination Polymer with Bridging Ligand Containing Sulfanyl Linker

摘要

A new coordination polymer with sulfide moieties, [Co(ptmb)2]·0.25H2O (ptmb＝4-(4-pyridylthiomethyl)benzoate), was synthesized by self-assembly of Co(NO3)2·6H2O with Hptmb under solvothermal conditions. X-ray single crystal diffraction study shows that it is a 2D layer structure consisting of puckered rhombus grid with dimensions 1.175 nm×1.110 nm.