Dinuclear chiral vanadium catalysts for oxidative coupling of 2-naphthols via a dual activation mechanism

摘要

This review describes our recent efforts in the development of chiral dinuclear vanadium complexes that work as dual activation catalysts for the oxidative coupling of 2-naphthols. The dinuclear vanadium(Ⅳ) complex (R_a,S,S)-la was prepared by complexation of VOSO_4 with the Schiff base derived from (R)-3,3'-diformyl-2,2'-dihydroxy-1,1'-binaphthyl (15) and (S)-tert-leucine. Since the dinuclear vanadium(Ⅳ) complex was found to be readily oxidized to afford a corresponding vanadium(Ⅴ) species during preparation in air, a new synthetic procedure using VOCl_3 has been applied towards dinuclear vanadium(Ⅴ) complexes (R_a,S,S)-2 and (R_a,S,S)-3. To the best of our knowledge, (R_a,S,S)-la, 2 and 3 show considerably higher catalytic activity than previously reported vanadium complexes for the oxidative coupling of 2-naphthols.