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Solvent-induced configuration mixing and triplet excited state inversion exemplified in a Pt(Ⅱ) complex

机译:Pt(Ⅱ)配合物中的溶剂诱导构型混合和三重态激发态反演

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摘要

The present study provides clear-cut experimental evidence for solvent-induced configuration mixing and complete triplet state inversion at room temperature in a Pt(Ⅱ) charge transfer complex bearing a combination of energetically proximate charge transfer and intraligand triplet excited states.
机译:本研究为溶剂诱导的构型混合和室温下Pt(Ⅱ)电荷转移复合物的完全三重态反转提供了明确的实验证据,该Pt(Ⅱ)电荷转移复合物具有能量上接近的电荷转移和配体内三重态激发态。

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