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首页> 外文期刊>Chemical Communications >Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)_3L] (Ln = Sm, Eu, Gd, Tb and Dy)
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Single-ion magnets based on mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)_3L] (Ln = Sm, Eu, Gd, Tb and Dy)

机译：基于单核镧系元素与手性席夫碱配体[Ln（FTA）_3L]（Ln = Sm，Eu，Gd，Tb和Dy）的单离子磁体

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摘要

A series of mononuclear lanthanide complexes with chiral Schiff base ligands [Ln(FTA)_3L] [Ln = Dy(1), Sm(2), Eu(3), Gd(4), and Tb(5), L = (S,S)-2,2'-Bis(4-benzyl-2-oxazoline)] were synthesized and characterized. Among these complexes, complex 1 represents the first example of mononuclear lanthanide complexes displaying single-ion magnet behavior and ferroelectricity.
机译：一系列具有手性席夫碱配体[Ln（FTA）_3L]的单核镧系元素络合物[Ln = Dy（1），Sm（2），Eu（3），Gd（4）和Tb（5），L =（合成并表征了S，S）-2，2′-双（4-苄基-2-恶唑啉）。在这些络合物中，络合物1代表单核镧系元素络合物的第一个实例，该化合物显示出单离子磁体行为和铁电性。

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  • 来源
    《Chemical Communications》 |2010年第17期|p.2929-2931|共3页
  • 作者

    Dong-Ping Li; Tian-Wei Wang; Cheng-Hui Li; Dong-Sheng Liu; Yi-Zhi Li; Xiao-Zeng You;

  • 作者单位

    State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China;

    rnState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China;

    rnState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China;

    rnState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China;

    rnState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China;

    rnState Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, P. R. China;

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