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Abrupt spin transition around room temperature and light induced properties in Fe~(II) complexes with N_4O_2 coordination sphere

机译:N_4O_2配位球在Fe〜(II)配合物中的室温自旋跃迁和光诱导性质

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摘要

Mononuclear spin-crossover complex Fe~Ⅱ(L)_2·CH_3OH (1·CH_3OH) and its desolvated product 1 exhibit abrupt spin transitions around room temperature. 1 also shows a light induced excited spin state trapping (LIESST) effect and a light induced thermal hysteresis (LITH) phenomenon at low temperature.
机译:单核自旋交联络合物Fe〜Ⅱ(L)_2·CH_3OH(1·CH_3OH)及其脱溶剂产物1在室温附近表现出突然的自旋转变。图1还示出了在低温下的光诱导的激发自旋俘获(LIESST)效应和光诱导的热滞后(LITH)现象。

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  • 来源
    《Chemical Communications》 |2010年第15期|p.2554-2556|共3页
  • 作者单位

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China Institute of Applied Chemistry, Xinjiang University, Urumqi 830046;

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China;

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China;

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China;

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China;

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China;

    Beijing National Laboratory for Molecular Sciences,State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering,Peking University, Beijing 100871, P. R. China;

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