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A rutile-type porous zinc(II)-phosphonocarboxylate framework: local proton transfer and size-selected catalysis

机译:金红石型多孔锌(膦)膦酸锌骨架:局部质子转移和尺寸选择催化

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摘要

The layered-solvothermal synthesis of zinc acetate dihydrate with 5-phosphonobenzene-1,3-dicarboxylic acid yields a three-dimensional rutile-type porous metal-organic framework, which is an anionic open-framework containing local proton transfer with hydrated protons and showing excellent size-selective properties.
机译:用5-膦酰基苯-1,3-二羧酸层状溶剂热合成乙酸锌二水合物,产生三维金红石型多孔金属有机骨架,该阴离子骨架为包含带质子和水化质子的局部质子转移的阴离子开放骨架出色的尺寸选择性能。

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  • 来源
    《Chemical Communications》 |2010年第7期|1100-1102|共3页
  • 作者单位

    Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China;

    Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China;

    Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China;

    Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China;

    Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, Shanghai (200433), China;

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  • 入库时间 2022-08-17 13:23:33

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