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Improvement of oxygen reduction reaction and methanol tolerance characteristics for PdCo electrocatalysts by Au alloying and CO treatment

机译:金合金化和CO处理改善PdCo电催化剂的氧还原反应和甲醇耐受性

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摘要

The mass ORR activity of CO heat-treated PdCoAu/C catalysts, compared to Pd/C, is enhanced approximately 6-fold, and even 25-fold in a methanol containing environment due to the formation of delicate PdCo and PdAu alloys enriched in the core and PdAu alloy species enriched on the shell structure.
机译:与Pd / C相比,在含甲醇的环境中,CO热处理的PdCoAu / C催化剂的质量ORR活性提高了约6倍,甚至提高了25倍,这是因为形成了富含PdCo和PdAu的精细合金。核和PdAu合金物质在壳结构上富集。

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  • 来源
    《Chemical Communications》 |2011年第43期|p.11927-11929|共3页
  • 作者单位

    Institute of Materials Science and Engineering, National Central University, Taoyuan 32001, Taiwan;

    Institute of Materials Science and Engineering, National Central University, Taoyuan 32001, Taiwan;

    Institute of Materials Science and Engineering, National Central University, Taoyuan 32001, Taiwan;

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  • 入库时间 2022-08-17 13:22:49

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