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Photosensitizing catalysis of the B_(12) complex without an additional photosensitizer

机译:没有额外的光敏剂的B_(12)配合物的光敏催化

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摘要

A cobalamin derivative, heptamethyl cobyrinate perchlorate, was activated by UV light irradiation to form a Co(I) species in the presence of triethanolamine and used for a dechlorination reaction, and this photochemical reaction was accelerated in an ionic liquid.
机译:在三乙醇胺存在下,用紫外线照射钴胺素衍生物高氯酸七甲酯,以形成Co(I)物种,并用于脱氯反应,并且该光化学反应在离子液体中被加速。

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  • 来源
    《Chemical Communications》 |2011年第39期|p.10921-10923|共3页
  • 作者单位

    Department of Chemistry and Biochemistry,Graduate School of Engineering, Kyushu University,Motooka, Fukuoka 819-0395, Japan;

    Department of Chemistry and Biochemistry,Graduate School of Engineering, Kyushu University,Motooka, Fukuoka 819-0395, Japan;

    Department of Chemistry and Biochemistry,Graduate School of Engineering, Kyushu University,Motooka, Fukuoka 819-0395, Japan;

    Department of Chemistry and Biochemistry,Graduate School of Engineering, Kyushu University,Motooka, Fukuoka 819-0395, Japan;

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