UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

Roy T. McBurney; Alexandra M. Z. Slawin; Laura A. Smart; Yanping Yu; John C. Walton

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UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

机译：紫外线促进的由肟基碳酸亚胺基合成的菲啶

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Oxime carbonates were found to be excellent precursors for the clean and direct generation of iminyl radicals under UV irradiation. Suitably functionalised iminyls underwent cyclisations yielding various phenanthridines and also substituted quinolines and isoquinolines. EPR and X-ray analyses of oxime carbonates provided insight into the mechanism.

机译：已发现肟肟酸盐是在紫外线照射下干净，直接生成亚胺基的极好前体。合适地官能化的亚氨基进行环化，产生各种菲啶以及取代的喹啉和异喹啉。碳酸盐肟的EPR和X射线分析提供了对该机理的深入了解。

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《Chemical Communications》 |2011年第28期|p.7974-7976|共3页
作者
Roy T. McBurney; Alexandra M. Z. Slawin; Laura A. Smart; Yanping Yu; John C. Walton;
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School of Chemistry, University of St. Andrews, EastChem,St. Andrews, Fife, KY16 9ST, UK;

School of Chemistry, University of St. Andrews, EastChem,St. Andrews, Fife, KY16 9ST, UK;

School of Chemistry, University of St. Andrews, EastChem,St. Andrews, Fife, KY16 9ST, UK;

School of Chemistry, University of St. Andrews, EastChem,St. Andrews, Fife, KY16 9ST, UK;

School of Chemistry, University of St. Andrews, EastChem,St. Andrews, Fife, KY16 9ST, UK;

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UV promoted phenanthridine syntheses from oxime carbonate derived iminyl radicals

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