Chiral properties of tetrathiatriarylmethyl spin probes

Benoit Driesschaert; Raphaeel Robiette; Fabio Lucaccioni; Bernard Gallez; Jacqueline Marchand-Brynaert

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Chiral properties of tetrathiatriarylmethyl spin probes

机译：四硫代三芳基甲基自旋探针的手性

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We report that tetrathiatriarylmethyl (trityl) EPR probes are chiral molecules at room temperature, the two stereoisomers that differ in their helicity being configurationally stable enough to be separated and stored independently.

机译：我们报告说，四硫代三芳基甲基（三苯甲基）EPR探针在室温下是手性分子，其螺旋度不同的两个立体异构体在结构上足够稳定，可以分离并独立存储。

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来源
《Chemical Communications》 |2011年第16期|p.4793-4795|共3页
作者
Benoit Driesschaert; Raphaeel Robiette; Fabio Lucaccioni; Bernard Gallez; Jacqueline Marchand-Brynaert;
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作者单位

Institute of Condensed Matter and Nanosciences (IMCN),Molecules, Solids and Reactivity (MOST), Universite Catholique deLouvain, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium,Louvain Drug Research Institute (LDRI), Biomedical Magnetic Resonance Section, Universite Catholique de Louvain,Avenue Mounier 73.40, B-1200 Bruxelles, Belgium;

Institute of Condensed Matter and Nanosciences (IMCN),Molecules, Solids and Reactivity (MOST), Universite Catholique deLouvain, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium;

Institute of Condensed Matter and Nanosciences (IMCN),Molecules, Solids and Reactivity (MOST), Universite Catholique deLouvain, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium;

Louvain Drug Research Institute (LDRI), Biomedical Magnetic Resonance Section, Universite Catholique de Louvain,Avenue Mounier 73.40, B-1200 Bruxelles, Belgium;

Institute of Condensed Matter and Nanosciences (IMCN),Molecules, Solids and Reactivity (MOST), Universite Catholique deLouvain, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium;

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入库时间 2022-08-17 13:22:19

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1. Dextran-conjugated tetrathiatriarylmethyl radicals as biocompatible spin probes for EPR spectroscopy and imaging [J] . Poncelet Martin, Driesschaert Benoit, Tseytlin Oxana, Bioorganic and Medicinal Chemistry Letters . 2019,第14期

机译：葡聚糖缀合的四硫胺甲基自由基作为EPR光谱和成像的生物相容性旋转探针
2. New Spin Probes: Tri- and Hexacationic Derivatives of Stable Tetrathiatriarylmethyl Radicals [J] . Trukhin D. V., Rogozhnikova O. Yu., Troitskaya T. I., Russian Journal of Organic Chemistry . 2019,第3期

机译：新的旋转探针：稳定四硫甲酰基的三分和六分析衍生物
3. Highlighting spin selectivity properties of chiral electrode surfaces from redox potential modulation of an achiral probe under an applied magnetic field [J] . Tiziana Benincori, Serena Arnaboldi, Mirko Magni, Chemical science . 2019,第9期

机译：在施加磁场的情况下通过非手性探针的氧化还原电位调制突出手性电极表面的自旋选择性
4. Universal near-field spin properties of polarized and chiral dipoles [C] . Farid Kalhor, Zubin Jacob United States National Committee of URSI National Radio Science Meeting . 2018

机译：极化和手性偶极子的通用近场自旋特性
5. Probing the enhanced superconductivity and chiral edge current in spin-triplet superconductor strontium ruthenate. [D] . Ying, Yiqun Alex. 2012

机译：探索自旋三重态超导体钌酸锶中增强的超导性和手性边缘电流。
6. Highlighting spin selectivity properties of chiral electrode surfaces from redox potential modulation of an achiral probe under an applied magnetic field [O] . Tiziana Benincori, Serena Arnaboldi, Mirko Magni, 2019

机译：在施加磁场的情况下通过非手性探针的氧化还原电位调制突出手性电极表面的自旋选择性
7. Dextran-conjugated tetrathiatriarylmethyl radicals as biocompatible spin probes for EPR spectroscopy and imaging [O] . Martin Poncelet, Benoit Driesschaert, Oxana Tseytlin, 2019

机译：葡聚糖缀合的四硫胺甲基作为EPR光谱和成像的生物相容性旋转探针

Chiral properties of tetrathiatriarylmethyl spin probes

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