Unexpected manganese(Ⅲ) acetate-mediated reactions of β-enamino carbonyl compounds with 1-(pyridin-2-yl)-enones under mechanical milling conditions

Zi Liu; Guang-Peng Fan; Guan-Wu Wang

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Unexpected manganese(Ⅲ) acetate-mediated reactions of β-enamino carbonyl compounds with 1-(pyridin-2-yl)-enones under mechanical milling conditions

机译：机械研磨条件下意外的乙酸锰（Ⅲ）介导的β-烯氨基羰基化合物与1-（吡啶-2-基）-烯酮的反应

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The solvent-free reactions of β-enamino carbonyl compounds with 1-(pyridin-2-yl)-enones in the presence of manganese(Ⅲ) acetate dihydrate unexpectedly afforded 2-acyl-3-aryl-6,7-dihydro-4(5H)-benzofuran derivatives under mechanical milling conditions.

机译：β-烯氨基羰基化合物与1-（吡啶-2-基）-烯酮在二水合乙酸锰（Ⅲ）存在下的无溶剂反应出乎意料地提供了2-酰基-3-芳基-6,7-二氢-4机械研磨条件下的（5H）-苯并呋喃衍生物。

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《Chemical Communications》 |2012年第95期|11665-11667|共3页
作者
Zi Liu; Guang-Peng Fan; Guan-Wu Wang;
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Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China;

Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China;

Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry, and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China,State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu 730000, P. R. China;

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2. Radical reactions of [60]fullerene with beta-enamino carbonyl compounds mediated by manganese(III) acetate [J] . Wang GW, Yang HT, Miao CB, Organic & biomolecular chemistry . 2006,第13期

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Unexpected manganese(Ⅲ) acetate-mediated reactions of β-enamino carbonyl compounds with 1-(pyridin-2-yl)-enones under mechanical milling conditions

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