Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and ~(183)W NMR studies

Maxim N. Sokolov; Sergey A. Adonin; Pavel A. Abramov; Dmitry A. Mainichev; Nina F. Zakharchuk; Vladimir P. Fedin

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Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and ~(183)W NMR studies

机译：具有四铑-氧代核的聚氧钨酸盐的自组装：合成，结构和〜（183）W NMR研究

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A sandwich-type rhodium polyoxotungstate with unprecedented tetrarhodium-oxo core Na_(12)[(Rh_4(μ_3-O)_2(H_2O)_2(H_2W_9O_(33))_2]. 38H_2O (1) was obtained by hydrothermal reaction of rhodium(Ⅱ) acetate and sodium tungstate; crystal structure was determined by X-ray diffractometry and was confirmed by 183W NMR data; 1 is active in electrocatalytic water oxidation.

机译：通过铑的水热反应获得了具有前所未有的四铑-氧代核Na_（12）[（Rh_4（μ_3-O）_2（H_2O）_2（H_2W_9O_（33））_ 2]。的三明治型多铑铑。 Ⅱ）乙酸盐和钨酸钠；晶体结构由X射线衍射法测定并由183W NMR数据证实； 1在电催化水氧化中具有活性。

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《Chemical Communications》 |2012年第53期|p.6666-6668|共3页
作者
Maxim N. Sokolov; Sergey A. Adonin; Pavel A. Abramov; Dmitry A. Mainichev; Nina F. Zakharchuk; Vladimir P. Fedin;
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Nikolaev Institute of Inorganic Chemistry SB RAS, 630090,Prosp. Lavrentieva 3, Novosibirsk, Russia,Novosibirsk State University, 630090, ul.Pirogova 2, Novosibirsk,Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, 630090,Prosp. Lavrentieva 3, Novosibirsk, Russia,Novosibirsk State University, 630090, ul.Pirogova 2, Novosibirsk,Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, 630090,Prosp. Lavrentieva 3, Novosibirsk, Russia,Novosibirsk State University, 630090, ul.Pirogova 2, Novosibirsk,Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, 630090,Prosp. Lavrentieva 3, Novosibirsk, Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, 630090,Prosp. Lavrentieva 3, Novosibirsk, Russia;

Nikolaev Institute of Inorganic Chemistry SB RAS, 630090,Prosp. Lavrentieva 3, Novosibirsk, Russia,Novosibirsk State University, 630090, ul.Pirogova 2, Novosibirsk,Russia;

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Self-assembly of polyoxotungstate with tetrarhodium-oxo core: synthesis, structure and ~(183)W NMR studies

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