Microwave-Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin-Type Polyoxotungstates: One-Step Synthesis, ~(99)Ru, ~(183)W NMR Characterization and Catalytic Activity of [PW_(11)O_(39)Ru~(II)(DMSO)]~(5-)

Alessandro Bagno; Marcella Bonchio; Andrea Sartorel; Gianfranco Scorrano

首页> 外文期刊>European journal of inorganic chemistry >Microwave-Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin-Type Polyoxotungstates: One-Step Synthesis, ~(99)Ru, ~(183)W NMR Characterization and Catalytic Activity of [PW_(11)O_(39)Ru~(II)(DMSO)]~(5-)

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Microwave-Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin-Type Polyoxotungstates: One-Step Synthesis, ~(99)Ru, ~(183)W NMR Characterization and Catalytic Activity of [PW_(11)O_(39)Ru~(II)(DMSO)]~(5-)

机译：微波辅助将钌快速掺入La的Keggin型多氧钨酸盐中：[PW_（11）O_（39）Ru〜（II）的一步合成，〜（99）Ru，〜（183）W NMR表征和催化活性（DMSO）]〜（5-）

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Microwave irradiation for 15 minutes allowed the highly selective hydrothermal synthesis of the diamagnetic, air-stable oxidation catalyst [PW_(11)O_(39)Ru~(II)(DMSO)]~(5-), as confirmed by ~1H, ~(31)P, ~(99)Ru and ~(183)W NMR techniques.

机译：微波辐照15分钟可以使高选择性水热合成抗磁性，空气稳定的氧化催化剂[PW_（11）O_（39）Ru〜（II）（DMSO）]〜（5-），由〜1H证实，〜（31）P，〜（99）Ru和〜（183）W NMR技术。

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《European journal of inorganic chemistry》 |2000年第1期|共4页
作者
Alessandro Bagno; Marcella Bonchio; Andrea Sartorel; Gianfranco Scorrano;
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正文语种 eng
中图分类无机化学;
关键词
polyoxometalates; ruthenium; homogeneous catalysis; oxidations; microwaves;

机译：多金属氧酸盐;钌;均相催化;氧化;微波;

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1. Microwave-Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin-Type Polyoxotungstates: One-Step Synthesis, ~(99)Ru, ~(183)W NMR Characterization and Catalytic Activity of [PW_(11)O_(39)Ru~(II)(DMSO)]~(5-) [J] . Alessandro Bagno, Marcella Bonchio, Andrea Sartorel, European journal of inorganic chemistry . 2000,第1期

机译：微波辅助将钌快速掺入La的Keggin型多氧钨酸盐中：[PW_（11）O_（39）Ru〜（II）的一步合成，〜（99）Ru，〜（183）W NMR表征和催化活性（DMSO）]〜（5-）
2. Determination of α-Keggin structure of [GeW_(11)O_(39)Ru~(III)(H_2O)]~(5-). Reaction of [GeW_(11)O_(39)Ru_(III)(H_2O)]~(5-) with dimethyl sulfoxide to form [GeW_(11)O_(39)Ru~(III)(dmso)]~(5-) and their structural characterization [J] . Ogo S., Shimizu N., Ozeki T., Dalton transactions: An international journal of inorganic chemistry . 2013,第7期

机译：[GeW_（11）O_（39）Ru〜（III）（H_2O）]〜（5-）的α-Keggin结构的确定。 [GeW_（11）O_（39）Ru_（III）（H_2O）]〜（5-）与二甲亚砜反应形成[GeW_（11）O_（39）Ru〜（III）（dmso）]〜（5 -）及其结构表征
3. Determination of α-Keggin structure of [GeW_(11)O_(39)Ru~(III)(H_2O)]~(5-). Reaction of [GeW_(11)O_(39)Ru_(III)(H_2O)]~(5-) with dimethyl sulfoxide to form [GeW_(11)O_(39)Ru~(III)(dmso)]~(5-) and their structural characterization [J] . Ogo S., Shimizu N., Ozeki T., Dalton transactions: An international journal of inorganic chemistry . 2013,第7期

机译：[GeW_（11）O_（39）Ru〜（III）（H_2O）]〜（5-）的α-Keggin结构的确定。 [GeW_（11）O_（39）Ru_（III）（H_2O）]〜（5-）与二甲亚砜反应形成[GeW_（11）O_（39）Ru〜（III）（dmso）]〜（5 -）及其结构表征
4. Synthesis and chemical-pharmacological characterization of the antimetastatic NAMI-A-type Ru(III) complexes (Hdmtp)(trans-RuCI4(dmso-S)(dmtp)), (Na)(trans-RuCI4(dmso-S)(dmtp)) and (mer-RuCI3(H2O)(dmso-S)(dmtp)) (dmtp=5, 7-dimethyl(1, 2, 4)triazolo(1, 5- [O] . -1

机译：抗致致动纳米-A型Ru（III）配合物（HDMTP）（Trans-Ruci4（DMSO-S）（DMTP））（NA）（DMSO-S）（DMTP）的合成和化学药物表征（DMTP）（DMTP ））和（MER-RUCI3（H2O）（DMSO-S）（DMTP））（DMTP = 5,7-二甲基（1,2,4）三唑唑（1,5-

Microwave-Assisted Rapid Incorporation of Ruthenium into Lacunary Keggin-Type Polyoxotungstates: One-Step Synthesis, ~(99)Ru, ~(183)W NMR Characterization and Catalytic Activity of [PW_(11)O_(39)Ru~(II)(DMSO)]~(5-)

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