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Electrocatalytic oxidation of alcohols by a carbon-supported Rh porphyrin

机译:碳载铑卟啉对醇的电催化氧化

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摘要

A Rh porphyrin on carbon black was shown to catalyze the electro-oxidation of several aliphatic alcohols (ethanol, 1-propanol, and 2-propanol) and benzyl alcohols. The overpotentials for alcohol oxidation were very low. The reaction mechanism and substrate specificity are discussed.
机译:炭黑上的Rh卟啉被证明可催化几种脂肪醇(乙醇,1-丙醇和2-丙醇)和苯甲醇的电氧化。醇氧化的过电位非常低。讨论了反应机理和底物特异性。

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  • 来源
    《Chemical Communications》 |2012年第36期|p.4353-4355|共3页
  • 作者单位

    Research Institute for Ubiquitous Energy Devices,National Institute of Advanced Industrial Science and Technology (AIST),1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan;

    Research Institute for Ubiquitous Energy Devices,National Institute of Advanced Industrial Science and Technology (AIST),1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan;

    Research Institute for Ubiquitous Energy Devices,National Institute of Advanced Industrial Science and Technology (AIST),1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan;

    Research Institute for Ubiquitous Energy Devices,National Institute of Advanced Industrial Science and Technology (AIST),1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan;

    Research Institute for Ubiquitous Energy Devices,National Institute of Advanced Industrial Science and Technology (AIST),1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan;

    Research Institute for Ubiquitous Energy Devices,National Institute of Advanced Industrial Science and Technology (AIST),1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan;

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  • 入库时间 2022-08-17 13:20:30

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