A smart porphyrin cage for recognizing azide anions

Jianhong Zhang; Yongjun Li; Wenlong Yang; Sui-Wai Lai; Chunjie Zhou; Huibiao Liu; Chi-Ming Che; Yuliang Li

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A smart porphyrin cage for recognizing azide anions

机译：用于识别叠氮化物阴离子的智能卟啉笼

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摘要

A smart porphyrin cage that can recognize azide anions by the changes of ~1H NMR spectra was synthesized by CuAAC "click" reaction in high yield.

机译：通过CuAAC“点击”反应以高收率合成了一个智能的卟啉笼，该笼可通过〜1H NMR光谱的变化识别叠氮化物阴离子。

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来源
《Chemical Communications》 |2012年第30期|p.3602-3604|共3页
作者
Jianhong Zhang; Yongjun Li; Wenlong Yang; Sui-Wai Lai; Chunjie Zhou; Huibiao Liu; Chi-Ming Che; Yuliang Li;
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作者单位

CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190,P. R. China,Graduate University of Chinese Academy of Sciences,Beijing, 100080, P. R. China;

CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190,P. R. China;

CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190,P. R. China,Graduate University of Chinese Academy of Sciences,Beijing, 100080, P. R. China;

Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road,Hong Kong SAR, P. R. China;

CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190,P. R. China,Graduate University of Chinese Academy of Sciences,Beijing, 100080, P. R. China;

CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190,P. R. China;

Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road,Hong Kong SAR, P. R. China;

CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Science (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190,P. R. China;

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1. Triazole- and triazolium-containing porphyrin-cages for optical anion sensing [J] . Gilday L.C., White N.G., Beer P.D. Dalton transactions: An international journal of inorganic chemistry . 2012,第23期

机译：含三唑和三唑鎓的卟啉笼用于光学阴离子感测
2. Reactions of Unsaturated Azides; Part 2211 The Alkyne Azide Click Chemistry as a Synthetic Tool for the Generation of Cage-Like Triazole Compounds [J] . Klaus Banert, Jens Wutke, Tobias Riiffer, Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2008,第16期

机译：不饱和叠氮化物的反应; 2211部分：炔烃叠氮点击化学作为合成笼子状三唑化合物的合成工具
3. p-Carborane Conjugation in Radical Anions of Cage–Cage and Cage–Phenyl Compounds [J] . Andrew R. Cook, Michal Valá?ek, Alison M. Funston, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2018,第3期

机译：P - 在笼笼和笼苯基化合物的基团阴离子中的羰基团聚
4. FLUORESCENT RECOGNITION OF SCN- ANION BASED ON THE PORPHYRIN/PORPHYRIN COBALT (Ⅱ) SELF-ASSEMBLY SYSTEM [C] . . 2005

机译：基于卟啉/卟啉钴（Ⅱ）自组装系统的SCN-阴离子荧光识别
5. Tetradipicolyamine-substituted resorc[4]arene cavitands: I. Anion binding and transition metal assembled coordination cages and nanoarchitectures. II. Polymer inclusion membranes applied to anion separations. [D] . Gardner, Joseph S. 2005

机译：Tetradipicolyamine取代的间苯二酚[4]芳烃空洞：I.阴离子结合和过渡金属组装的配位笼和纳米结构。二。适用于阴离子分离的聚合物包合物膜。
6. Iron porphyrin catalysed light driven C–H bond amination and alkene aziridination with organic azides [O] . Yi-Dan Du, Cong-Ying Zhou, Wai-Pong To, 2020

机译：铁卟啉催化光从驱动C-H键胺化和烯烃叠氮化物质叠氮化物
7. Novel anion conductors - conductivity, thermodynamic stability and hydration of anion-substituted mayenite-type cage compounds C(12)A(7):X (X = O, OH, Cl, F, CN, S, N) [O] . Eufinger Jens-Peter, Schmidt Alexander, Lerch Martin, 2015

机译：新型阴离子导体-阴离子取代的钙铝石型笼状化合物C（12）A（7）：X（X = O，OH，Cl，F，CN，S，N）的电导率，热力学稳定性和水合
8. Fluorinated Dodecaphenylporphyrins: Synthetic and Electrochemical Studies Including the First Evidence of Intramolecular Electron Transfer Between an Fe(II) Porphyrin -Anion Radical and an Fe(I) Porphyrin;Inorganic Chemistry [R] . D'Souza, F. , Forsyth, T. P. , Fukuzumi, S. , 1998

机译：氟化十二烷基卟啉：合成和电化学研究，包括Fe（II）卟啉 - 阴离子自由基和Fe（I）卟啉之间的分子内电子转移的第一证据;无机化学

A smart porphyrin cage for recognizing azide anions

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