PHIP-label: parahydrogen-induced polarization in propargylglycine-containing synthetic oligopeptides

Marco Koerner; Grit Sauer; Andreas Heil; Daichi Nasu; Martin Empting; Daniel Tietze; Stephan Voigt; Heiko Weidler; Torsten Gutmann; Olga Avrutina; Harald Kolmar; Tomasz Ratajczyk; Gerd Buntkowsky

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PHIP-label: parahydrogen-induced polarization in propargylglycine-containing synthetic oligopeptides

机译：PHIP标签：含炔丙基甘氨酸的合成寡肽中对氢诱导的极化

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The unsaturated side chain of L-propargylglycine (Pra) was used to study parahydrogen-induced polarization (PHIP) in synthetic oligo-peptides. For the first time PHIP-induced NMR signal enhancement was demonstrated using model peptides bearing various functional side chains.

机译：L-炔丙基甘氨酸（Pra）的不饱和侧链用于研究合成寡肽中对氢诱导的极化（PHIP）。首次使用带有各种功能性侧链的模型肽证明了PHIP诱导的NMR信号增强。

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《Chemical Communications》 |2013年第71期|7839-7841|共3页
作者
Marco Koerner; Grit Sauer; Andreas Heil; Daichi Nasu; Martin Empting; Daniel Tietze; Stephan Voigt; Heiko Weidler; Torsten Gutmann; Olga Avrutina; Harald Kolmar; Tomasz Ratajczyk; Gerd Buntkowsky;
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TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TU Darmstadt, Clemens-Schoepf-lnstitut fuer Organische Chemie und Biochemie, Petersenstr, 22, Darmstadt, Germany;

TU Darmstadt, Clemens-Schoepf-lnstitut fuer Organische Chemie und Biochemie, Petersenstr, 22, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

TU Darmstadt, Clemens-Schoepf-lnstitut fuer Organische Chemie und Biochemie, Petersenstr, 22, Darmstadt, Germany;

TU Darmstadt, Clemens-Schoepf-lnstitut fuer Organische Chemie und Biochemie, Petersenstr, 22, Darmstadt, Germany;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany,Polish Academy of Sciences, Institute of Physical Chemistry, Kasprzaka 44/52, 01-224 Warszawa, Poland;

TV Darmstadt, Eduard-Zintl-Institut fuer Anorganische und Physikalische Chemie, Petersenstr, 20, Darmstadt, Germany;

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入库时间 2022-08-17 13:18:34

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1. Nuclear spin hyperpolarization with ansa-aminoboranes: a metal-free perspective for parahydrogen-induced polarization [J] . Zhivonitko Vladimir V., Sorochkina Kristina, Chernichenko Konstantin, Physical chemistry chemical physics: PCCP . 2016,第40期

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机译：Ansa-氨基硼烷的核自旋超极化：对氢诱导极化的无金属观点。
3. A theoretical basis for spontaneous polarization transfer in non-hydrogenative parahydrogen-induced polarization [J] . Ralph W. Adams, Simon B. Duckett, Richard A. Green, The Journal of Chemical Physics . 2009,第19期

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5. Part 1. Relative antioxidant efficiency of synthetic and natural compounds. Part 2. Synthesis, characterization of cysteine oligopeptides and assessment of their antioxidant activity [D] . Li, Chunyu 2005

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PHIP-label: parahydrogen-induced polarization in propargylglycine-containing synthetic oligopeptides

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