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A tetragonal prismatic {Co_(32)} nanocage based on thiacalixarene

机译：基于硫杂杯芳烃的四方棱柱形{Co_（32）}纳米笼

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摘要

A novel coordination nanocage was obtained with in situ-generated tetrazole ligands from the cobalt-thiacalix[4]arene system. Four in situ-generated 1,3-bis(2H-tetirazol-5-yl) benzene ligands bolster eight Gvcalix shuttle-cock-like secondary building units (SBUs) into a hollow tetragonal prism with a high surface area. The unprecedented {Co_(32)} nanocage presents the highest nudearity example.
机译：一种新颖的配位纳米笼是用原位生成的四唑配体从钴噻唑[4]芳烃体系中获得的。四个原位生成的1,3-双（2H-替硝唑-5-基）苯配体将八个Gvcalix穿梭-公鸡状二级建筑单元（SBU）支撑成具有高表面积的中空四棱柱。前所未有的{Co_（32）}纳米笼提出了最高的裸体度示例。

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  • 来源
    《Chemical Communications》 |2013年第60期|6785-6787|共3页
  • 作者

    Yanfeng Bi; Shentang Wang; Mei Liu; Shangchao Du; Wuping Liao;

  • 作者单位

    State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China;

    State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China;

    State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China,Graduate University of the Chinese Academy of Sciences, Beijing 100049, China;

    State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China,Graduate University of the Chinese Academy of Sciences, Beijing 100049, China;

    State Key Laboratory of Rare Earth Resource Utilization, ERC for the Separation and Purification of REs and Thorium, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China;

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  • 入库时间 2022-08-17 13:18:27

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