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首页> 外文期刊>Chemical Communications >Abrupt spin crossover in an iron(Ⅲ) quinolylsalicylaldimine complex: structural insights and solvent effects
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Abrupt spin crossover in an iron(Ⅲ) quinolylsalicylaldimine complex: structural insights and solvent effects

机译：铁（Ⅲ）喹啉基水杨醛亚胺络合物的突然自旋交叉：结构见解和溶剂效应

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摘要

The first Fe(Ⅲ) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-1)_2]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.
机译：据报道，第一个Fe（Ⅲ）qsal-X络合物在228 K处出现突然的完全自旋交叉，具有8 K的磁滞，据报道[Fe（qsal-1）_2] OTf。描述了在LS和HS状态以及自旋转变过程中MeOH溶剂化物的结构研究。

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  • 来源
    《Chemical Communications》 |2013年第56期|6340-6342|共3页
  • 作者

    David J. Harding; Wasinee Phonsri; Phimphaka Harding; Ian A. Gass; Keith S. Murray; Boujemaa Moubaraki; John D. Cashion; Lujia Liu; Shane G. Telfer;

  • 作者单位

    Molecular Technology Research Unit Cell, Walailak University, Thasala, Nakhon Si Thammarat, 80161, Thailand;

    Molecular Technology Research Unit Cell, Walailak University, Thasala, Nakhon Si Thammarat, 80161, Thailand;

    Molecular Technology Research Unit Cell, Walailak University, Thasala, Nakhon Si Thammarat, 80161, Thailand;

    Department of Chemistry, Monash University, Clayton, Melbourne, Victoria, 3800,Australia;

    Department of Chemistry, Monash University, Clayton, Melbourne, Victoria, 3800,Australia;

    Department of Chemistry, Monash University, Clayton, Melbourne, Victoria, 3800,Australia;

    Department of Physics, Monash University, Melbourne, Victoria, 3800, Australia;

    MacDiarmid Institute for Advanced Materials and Nanotechnology, Institute of Fundamental Sciences, Massey University, Palmerston North, New Zealand;

    MacDiarmid Institute for Advanced Materials and Nanotechnology, Institute of Fundamental Sciences, Massey University, Palmerston North, New Zealand;

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  • 入库时间 2022-08-17 13:18:31

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